Propane Tank Math

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Introduction

Figure 1: Propane Heater I Just Purchased.

Figure 1: Propane Heater I Just Purchased (Source).

I have some woodworking I need to do, and my little woodshop is in my garage. Unfortunately, Minnesota is quite cold at the moment, and working in the garage is not comfortable. After decades of working out in the cold, I decided it is time to get a small heater to make things a bit more comfortable.

I have used propane for years with my barbecue grill, but I have never used it for heating a space. I know that there is an Ashland propane delivery provider for people who heat their space this way, but here I just went and got one when I was out. While at university many decades ago, I worked in construction, and we used propane heaters to make working in partially completed homes more comfortable in the winter. I went to Home Depot and purchased the propane heater shown in Figure 1. It is rated to put out 30K to 40K BTU/hr. This should provide enough heat to warm my garage so I can work in it comfortably. I like the fact that it is small, and I can easily store it during the summer. I have too much stuff to manage as it is, and I do not need any more big stuff.

Background

Definitions

Tare Weight (TW)
Tare weight, sometimes called unladen weight, is the weight of an empty vehicle or container (Source).
Commercial Propane
This product consists of a hydrocarbon mixture containing predominantly propane (Source).
Water Capacity (WC)
The water capacity is how much water the propane tank will hold in pounds. For example, the "WC" stamped on the tank followed by a number such as "47.6" means the tank will hold 47.6 pounds of water. (Source).

Tank Construction

Figure 2 shows the internal construction of a typical 20 lb propane tank.

Figure 2: Propane Tank Construction.

Figure 2: Propane Tank Construction (Source).

Appendix B provides some information on the how the pressure in a propane tank varies with temperature.

Analysis

Volume of Propane in a 20 lb Cylinder

My old propane tank is shown in Figure 3. It has a WC=47.6 lbs and TW=18 lbs.

Figure M: Rating on My Propane Tank.

Figure 3: Rating on My Propane Tank.

I can compute the weight and volume of propane in this tank as shown in Figure 4.

Figure M: Demonstration of Way a 20 lb Tank is Named Such.

Figure 4: Demonstration of Why a 20 lb Tank is Named Such.

20% Safety Margin

I found the following statement in this document.

A tank filled with a volume of 80% liquid phase at 0 C will be full at a temperature of 60 C. At the same time, the density of propane in the liquid phase decreases from 530 to 430g/l.

Requiring 20% of margin reserve allows the propane to expand when the temperature rises. Figure 5 shows how I confirmed this statement using the propane density versus temperature relationship I compute in Appendix A – I thought it was a bit messy to include in the main post.

Figure M: Verification of 60 C Temperature Rise Filling a Tank.

Figure 5: Verification of 60 C Temperature Rise Filling a Tank.

In Figure 5, I derive a rate of 1.9% volume expansion for every 10 F of temperature rise, which assumes a constant mass. The Wikipedia lists 1.5% volume expansion for every 10 F. My value is in the ballpark, but not as close as I like to be.

Operating Time At Maximum BTU Generation Rate

Figure 6 shows my estimate for the amount of heating time I should expect from a 20 lb tank of propane – 10.8 hours. The energy density of propane comes from this source.

Figure M: Estimate Run Time Calculation.

Figure 6: Estimate Run Time Calculation.

The 10.8 hour value is also quoted in the heater manual (Figure 7).

Figure 4: Heater Manual Run Time Specification.

Figure 7: Heater Manual Run Time Specification.

Conclusion

I like to understand a bit about any product I use. This analysis gave me a bit of insight into how propane is used for space heating.

Appendix A: Liquid Expansion Model

Since I wanted to understand how propane expands with temperature, I need some information. I found this excerpt on the web that provide a functional model based on curve-fitting data.

Eq. 1 \displaystyle \rho =A\cdot {{B}^{{-\left( {1-\frac{T}{{{{T}_{C}}}}} \right)\cdot n}}}

where

  • A, B, n, TC are curve-fit generated parameters.
  • T is the temperature in Kelvin.

Unfortunately, I was not able to find parameters for propane (C3H8). So I decided to put together my own model. The model of Equation 1 is a bit difficult to fit because it has some parameters that are not independent. For my work here, I will use the model shown in Equation 2.

Eq. 2 \displaystyle \rho (T)=\alpha\cdot {{\beta}^{{\gamma\cdot T}}}

where

  • α, β, and γ are curve-fit generated parameters.

I searched the web and found some density data points for commercial propane, which is not pure propane because it also contains other fuels like butane and methane. Figure 8 show the results of my curve-fitting exercise.

Figure M: My Curve-Fitting of Propane Density Data.

Figure 8: My Curve-Fitting of Propane Density Data.

Figure 9 graphically shows the quality of the curve-fit to the data. Note that in this limited temperature region, a linear model would have sufficed.

Figure M: Curve-Fit Vs. Raw Data.

Figure 9 Curve-Fit Vs. Raw Data.

Appendix B: Tank Pressure Vs. Temperature

Figure 10 shows how the tank pressure varies with temperature.

Figure M: Tank Presure Versus Temperature.

Figure 10: Tank Pressure Versus Temperature (Source).

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5 Responses to Propane Tank Math

  1. Pingback: Chemical Composition Of Liquid Air - Chemical Literature

  2. Barry Bailey says:

    where does the US Dot get the number 4.2 to multiply with the WC on the tank to get the pounds of propane in the tank to fill it? Apparently it accounts for the 80 percent fill of the tank.

    • mathscinotes says:

      Hi Barry,
      Sorry I am so slow to respond. My schedule is ridiculous.

      Tare Weight
      The empty weight of the cylinder (link).
      Water Capacity
      The capacity of the cylinder in pounds (link).

      The 4.2 represents the density of propane @ 60°F when expressed in lbs per gallon (link).

      The density of liquid propane at 25 °C (77 °F) is 0.493 g/cm3, which is equivalent to 4.11 pounds per U.S. liquid gallon or 493 g/L. Propane expands at 1.5% per 10 °F. Thus, liquid propane has a density of approximately 4.2 pounds per gallon (504 g/L) at 60 °F (15.6 °C).

      The capacity of the propane tank in gallons is computed by the following formula (link).

      \displaystyle V=\frac{W}{\rho }

      Note that US safety regulations limit the propane level to not exceed 42% of the water capacity of the tank (link).

      Time for an example calculation. A standard 20 lb (5 gal) propane cylinder has a WC = 47.6 lbs. You are not allowed to fill the tank with more than 47.6*0.42 = 20 lb of propane. Now stations do not fill tanks more than 80% for safety reasons (link).

      So the tank will hold 0.8*20/4.2 = 3.8 gallons of propane. This is at 60°F. The amount will vary with temperature.

      Hope this helps.

      mark

  3. harry booth says:

    if you have a 500 gal propane tank filled to 80% on an 80 degree day what % should you read on a 30 degree day and no propane was used. thank you

  4. joejoe says:

    A 20 lb tank with a wc 47.6 will hold 5.7 gal of liquid assuming water is 8.34 lbs/gal.. The capacity with 20% reduction is as follows... 5.7gal x .8 = 4.56 gal of useable capacity. 4.56 gal x 4.24 lbs/gal propane is equal to 20 lbs of propane. The tank will hold 20 lbs of propane and maintain 20% head space. To be clear a 20 lb tank will hold 5.7 gal of liquid and only be able to fill 4.56 gal of propane. Assuming standard atmosphere.

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